According to the mosaic scenario, relaxation in supercooled liquids is ruled by two competing mechanisms: surface tension, opposing the creation of local excitations, and entropy, providing the drive to the configurational rearrangement of a given region. We test this scenario through numerical simulations well below the Mode Coupling temperature. For an equilibrated configuration, we freeze all the particles outside a sphere and study the thermodynamics of this sphere. The frozen environment acts as a pinning field. Measuring the overlap between the unpinned and pinned equilibrium configurations of the sphere, we can see whether it has switched to a different state. We do not find any clear evidence of the mosaic scenario. Rather, our results seem compatible with the existence of a single (liquid) state. However, we find evidence of a growing static correlation length, apparently unrelated to the mosaic one.

Mosaic multistate scenario versus one-state description of supercooled liquids

Verrocchio, Paolo
2007-01-01

Abstract

According to the mosaic scenario, relaxation in supercooled liquids is ruled by two competing mechanisms: surface tension, opposing the creation of local excitations, and entropy, providing the drive to the configurational rearrangement of a given region. We test this scenario through numerical simulations well below the Mode Coupling temperature. For an equilibrated configuration, we freeze all the particles outside a sphere and study the thermodynamics of this sphere. The frozen environment acts as a pinning field. Measuring the overlap between the unpinned and pinned equilibrium configurations of the sphere, we can see whether it has switched to a different state. We do not find any clear evidence of the mosaic scenario. Rather, our results seem compatible with the existence of a single (liquid) state. However, we find evidence of a growing static correlation length, apparently unrelated to the mosaic one.
2007
A., Cavagna; T., Grigera; Verrocchio, Paolo
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11572/66124
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