The search for organic molecules on Mars is central to understanding the planet’s past habitability and potential for ancient life. Although organic molecules have previously been detected on Mars, their nature, origin and preservation mechanisms remain debated. On the floor of the Jezero crater—an ancient delta–lake system on Mars—the Perseverance rover detected Raman features that may be due to organic compounds spatially associated with sulfates, although their origin is uncertain. Here we report the detection of similar Raman features in the Jezero fan top and attribute them to polycyclic aromatic hydrocarbons based on comparisons with laboratory data. We propose that these polycyclic aromatic hydrocarbons may have formed through endogenous igneous processes and were subsequently preserved by sulfate precipitation. These findings align with previous studies on Martian meteorites and at Gale crater, underscoring the role of sulfates in preserving organic matter on Mars. Returning these samples to Earth would be key to assess their astrobiological relevance.

Evidence for polycyclic aromatic hydrocarbons detected in sulfates at Jezero crater by the Perseverance rover / Fornaro, Teresa; Sharma, Sunanda; Jakubek, Ryan S.; Poggiali, Giovanni; Brucato, John Robert; Bhartia, Rohit; Steele, Andrew; Murphy, Ashley E.; Tice, Michael M.; Schulte, Mitchell D.; Hand, Kevin P.; Fries, Marc D.; Abbey, William J.; Alberini, Andrew; Alvarado-Jiménez, Daniela; Benison, Kathleen C.; Berger, Eve L.; Biancalani, Sole; Brown, Adrian J.; Broz, Adrian P.; Buckley, Wayne P.; Buckner, Denise K.; Burton, Aaron S.; Bykov, Sergei V.; Cardarelli, Emily L.; Cloutis, Edward A.; Connell, Stephanie A.; Garcia-Florentino, Cristina; Gómez, Felipe; Haney, Nikole C.; Lee, Carina; Lino, Valeria; Manini, Paola; Mccubbin, Francis M.; Minitti, Michelle E.; Morris, Richard V.; Phua, Yu Yu; Randazzo, Nicolas; Razzell Hollis, Joseph; Renzi, Francesco; Siljeström, Sandra; Simon, Justin I.; Srivastava, Anushree; Tasinato, Nicola; Uckert, Kyle; Wiens, Roger C.; Williams, Amy J.. - In: NATURE ASTRONOMY. - ISSN 2397-3366. - 9:11(2025), pp. 1648-1661. [10.1038/s41550-025-02638-z]

Evidence for polycyclic aromatic hydrocarbons detected in sulfates at Jezero crater by the Perseverance rover

Biancalani, Sole;
2025-01-01

Abstract

The search for organic molecules on Mars is central to understanding the planet’s past habitability and potential for ancient life. Although organic molecules have previously been detected on Mars, their nature, origin and preservation mechanisms remain debated. On the floor of the Jezero crater—an ancient delta–lake system on Mars—the Perseverance rover detected Raman features that may be due to organic compounds spatially associated with sulfates, although their origin is uncertain. Here we report the detection of similar Raman features in the Jezero fan top and attribute them to polycyclic aromatic hydrocarbons based on comparisons with laboratory data. We propose that these polycyclic aromatic hydrocarbons may have formed through endogenous igneous processes and were subsequently preserved by sulfate precipitation. These findings align with previous studies on Martian meteorites and at Gale crater, underscoring the role of sulfates in preserving organic matter on Mars. Returning these samples to Earth would be key to assess their astrobiological relevance.
2025
11
Fornaro, Teresa; Sharma, Sunanda; Jakubek, Ryan S.; Poggiali, Giovanni; Brucato, John Robert; Bhartia, Rohit; Steele, Andrew; Murphy, Ashley E.; Tice,...espandi
Evidence for polycyclic aromatic hydrocarbons detected in sulfates at Jezero crater by the Perseverance rover / Fornaro, Teresa; Sharma, Sunanda; Jakubek, Ryan S.; Poggiali, Giovanni; Brucato, John Robert; Bhartia, Rohit; Steele, Andrew; Murphy, Ashley E.; Tice, Michael M.; Schulte, Mitchell D.; Hand, Kevin P.; Fries, Marc D.; Abbey, William J.; Alberini, Andrew; Alvarado-Jiménez, Daniela; Benison, Kathleen C.; Berger, Eve L.; Biancalani, Sole; Brown, Adrian J.; Broz, Adrian P.; Buckley, Wayne P.; Buckner, Denise K.; Burton, Aaron S.; Bykov, Sergei V.; Cardarelli, Emily L.; Cloutis, Edward A.; Connell, Stephanie A.; Garcia-Florentino, Cristina; Gómez, Felipe; Haney, Nikole C.; Lee, Carina; Lino, Valeria; Manini, Paola; Mccubbin, Francis M.; Minitti, Michelle E.; Morris, Richard V.; Phua, Yu Yu; Randazzo, Nicolas; Razzell Hollis, Joseph; Renzi, Francesco; Siljeström, Sandra; Simon, Justin I.; Srivastava, Anushree; Tasinato, Nicola; Uckert, Kyle; Wiens, Roger C.; Williams, Amy J.. - In: NATURE ASTRONOMY. - ISSN 2397-3366. - 9:11(2025), pp. 1648-1661. [10.1038/s41550-025-02638-z]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11572/478142
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