Supercooled Condensation Droplets Sliding on Frost: Origin and Anti-Frosting Effect Observed on Cotinus Coggygria Leaf

Fascinated by the purple color, water-repellent, and self-cleaning properties of Cotinus coggygria Scop. leaves, we studied their morphology, wetting, and condensation frosting. Wax nanotubules confer high contact angles, enabling coalescence-induced condensation droplet (out-of-plane) jumping, which, as known, contributes to slowing down frost. Another type of movement—this time in-plane—becomes predominant in reducing the frosting velocity (vfrost) within a sub-cooling temperature range. Specifically, supercooled droplets slide toward the frost bridges upon contact, moving in the opposite direction to frost propagation. Between −11 and −2°C, Sliding on Frost (SoF) shifts from being rare to very frequent, reducing vfrost/vbridge from approximately 4 to 1, respectively. Using high-speed microscopy, we observed that the advancing contact angle of supercooled water on ice decreases with temperature. We describe the primary role of this behavior in SoF with a model that accounts for the f...