The electrochemical strategies with green electrocatalysts propose a selective, steady, and sensitive direction for the trace analytes sensing, hydrogen evolution reaction (HER), and oxygen evolution reaction (OER) applications. Herein, Honeycomb Polypore biomass waste-derived NaOH-activated porous nanocarbon material was synthesized, which performs as a multifunctional electrocatalyst for Hg2+ sensing and water-splitting reactions with the support of graphite and Nafion composite. The optimized nanocomposite shows high electrochemical activity for the redox reaction of Hg2+ in 0.1 M phosphate-buffered saline of 5.0 pH with a lower limit of detection value of 2.309 nM, good stability, reproducibility, and anti-interference activity. For water-splitting reactions, the optimized nanocomposite shows better overpotential values of 0.447 V (HER in 0.5 M H2SO4) and 0.305 V (OER in 0.5 M KOH) at 10.0 mA/cm2 of current density. Also, the lower Tafel slope values of 0.089 V/decade and 0.075 V/decade of the optimum electrocatalyst signify superior proficiency towards the HER and OER activities, respectively. These outcomes validate the materials’ excellent multifunctional activity for Hg2+ detection in different water samples and water-splitting reactions, boosting their potential for environmental safety and energy production.
Honeycomb polypore biomass-derived activated porous carbon nanosheets/graphite/nafion composite: Green and sensitive electrocatalyst for nanomolar detection of Hg2+ ions and water-splitting reactions / Hareesha, N.; Soumya, D. M.; Mounesh, ; Manjunatha, J. G.; Rohit, R. N.; Manikanta, P.; Varun, D. N.; Ataollahi, N.; Thippeswamy, B. A.; Pramoda, K.; Nagaraja, B. M.. - In: JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING. - ISSN 2213-3437. - 2024, 12:5(2024), pp. 1-17. [10.1016/j.jece.2024.113584]
Honeycomb polypore biomass-derived activated porous carbon nanosheets/graphite/nafion composite: Green and sensitive electrocatalyst for nanomolar detection of Hg2+ ions and water-splitting reactions
Ataollahi N.;
2024-01-01
Abstract
The electrochemical strategies with green electrocatalysts propose a selective, steady, and sensitive direction for the trace analytes sensing, hydrogen evolution reaction (HER), and oxygen evolution reaction (OER) applications. Herein, Honeycomb Polypore biomass waste-derived NaOH-activated porous nanocarbon material was synthesized, which performs as a multifunctional electrocatalyst for Hg2+ sensing and water-splitting reactions with the support of graphite and Nafion composite. The optimized nanocomposite shows high electrochemical activity for the redox reaction of Hg2+ in 0.1 M phosphate-buffered saline of 5.0 pH with a lower limit of detection value of 2.309 nM, good stability, reproducibility, and anti-interference activity. For water-splitting reactions, the optimized nanocomposite shows better overpotential values of 0.447 V (HER in 0.5 M H2SO4) and 0.305 V (OER in 0.5 M KOH) at 10.0 mA/cm2 of current density. Also, the lower Tafel slope values of 0.089 V/decade and 0.075 V/decade of the optimum electrocatalyst signify superior proficiency towards the HER and OER activities, respectively. These outcomes validate the materials’ excellent multifunctional activity for Hg2+ detection in different water samples and water-splitting reactions, boosting their potential for environmental safety and energy production.File | Dimensione | Formato | |
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