Cu2ZnSnS4 (CZTS) is seen as a microstructure electrode due to its high energy density when applied in lithium rechargeable batteries such as lithium-ion batteries (LIB) and lithium sulfur batteries (LSB). This review provides a systematic observation to evaluate the CZTS electrode capabilities from the perspective of electrode composition and its performance in lithium rechargeable batteries. This review starts by focusing on state-of-art lithium rechargeable batteries using common sulfur/sulfide-based materials reported from literature. The relation between the LSB performance with the active materials - sulfur, binder, solvents, electrolytes, and conducting additive used for lithium sulfide (Li2S) formation required for charge transfer properties is discussed critically. The following section discusses the current progress on CZTS-based electrode in lithium rechargeable batteries and it is found that the highest capacity obtained with improved interfacial compatibility is 1802 mAh g1 by hydrothermal techniques using 1 M LiPF6 in EC/EMC/DMC electrolyte. These properties have made sulfide component in CZTS structure as a great substitute to conventional sulfur/sulfide-based active materials. Therefore, CZTS has become a promising and huge potential electrode in lithium rechargeable batteries.

Cu2ZnSnS4‐Based Electrode as an Improvement Strategy for Lithium Rechargeable Batteries: A Status Review / Hassan, Maryam; Imyrah, Nur; Chelvanathan, Puvaneswaran; Ahmoum, Hassan; Scardi, Paolo; Ahmad, Azizan; Su'Ait, Mohd Sukor. - In: ENERGY TECHNOLOGY. - ISSN 2194-4288. - 2024, 12:6(2024), pp. 1-18. [10.1002/ente.202301173]

Cu2ZnSnS4‐Based Electrode as an Improvement Strategy for Lithium Rechargeable Batteries: A Status Review

Scardi, Paolo;
2024-01-01

Abstract

Cu2ZnSnS4 (CZTS) is seen as a microstructure electrode due to its high energy density when applied in lithium rechargeable batteries such as lithium-ion batteries (LIB) and lithium sulfur batteries (LSB). This review provides a systematic observation to evaluate the CZTS electrode capabilities from the perspective of electrode composition and its performance in lithium rechargeable batteries. This review starts by focusing on state-of-art lithium rechargeable batteries using common sulfur/sulfide-based materials reported from literature. The relation between the LSB performance with the active materials - sulfur, binder, solvents, electrolytes, and conducting additive used for lithium sulfide (Li2S) formation required for charge transfer properties is discussed critically. The following section discusses the current progress on CZTS-based electrode in lithium rechargeable batteries and it is found that the highest capacity obtained with improved interfacial compatibility is 1802 mAh g1 by hydrothermal techniques using 1 M LiPF6 in EC/EMC/DMC electrolyte. These properties have made sulfide component in CZTS structure as a great substitute to conventional sulfur/sulfide-based active materials. Therefore, CZTS has become a promising and huge potential electrode in lithium rechargeable batteries.
2024
6
Hassan, Maryam; Imyrah, Nur; Chelvanathan, Puvaneswaran; Ahmoum, Hassan; Scardi, Paolo; Ahmad, Azizan; Su'Ait, Mohd Sukor
Cu2ZnSnS4‐Based Electrode as an Improvement Strategy for Lithium Rechargeable Batteries: A Status Review / Hassan, Maryam; Imyrah, Nur; Chelvanathan, Puvaneswaran; Ahmoum, Hassan; Scardi, Paolo; Ahmad, Azizan; Su'Ait, Mohd Sukor. - In: ENERGY TECHNOLOGY. - ISSN 2194-4288. - 2024, 12:6(2024), pp. 1-18. [10.1002/ente.202301173]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11572/407169
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