Electric field-assisted ion exchange process was carried out on an innovative soda magnesia silicate float glass by using a specifically realized equipment which allows to change the applied voltage and the polarity and to measure the flowing current. Parameters such as surface K/Na exchange rate, potassium penetration, inter-diffusion coefficient, residual stress and case depth were measured and correlated with the processing conditions. The results revealed a high propensity of the considered glass to be chemically strengthened and a beneficial effect of the applied electric field in terms of time and temperature. For treatment carried out at 410 °C potassium penetration depth in excess to 10 μm can be achieved in less than 5 min. By alternating the polarity, both sides can be homogeneously reinforced. When the duration of each single cycle at a certain polarity is increased, the potassium penetration depth increases although cycles longer than 10 min can be detrimental.

Electric-field assisted ion-exchange of innovative float glass / Pintori, Giovanna; Sglavo, Vincenzo Maria. - In: JOURNAL OF NON-CRYSTALLINE SOLIDS. - ISSN 0022-3093. - STAMPA. - 600:(2023), p. 121994. [10.1016/j.jnoncrysol.2022.121994]

Electric-field assisted ion-exchange of innovative float glass

Pintori, Giovanna
;
Sglavo, Vincenzo Maria
2023-01-01

Abstract

Electric field-assisted ion exchange process was carried out on an innovative soda magnesia silicate float glass by using a specifically realized equipment which allows to change the applied voltage and the polarity and to measure the flowing current. Parameters such as surface K/Na exchange rate, potassium penetration, inter-diffusion coefficient, residual stress and case depth were measured and correlated with the processing conditions. The results revealed a high propensity of the considered glass to be chemically strengthened and a beneficial effect of the applied electric field in terms of time and temperature. For treatment carried out at 410 °C potassium penetration depth in excess to 10 μm can be achieved in less than 5 min. By alternating the polarity, both sides can be homogeneously reinforced. When the duration of each single cycle at a certain polarity is increased, the potassium penetration depth increases although cycles longer than 10 min can be detrimental.
2023
Pintori, Giovanna; Sglavo, Vincenzo Maria
Electric-field assisted ion-exchange of innovative float glass / Pintori, Giovanna; Sglavo, Vincenzo Maria. - In: JOURNAL OF NON-CRYSTALLINE SOLIDS. - ISSN 0022-3093. - STAMPA. - 600:(2023), p. 121994. [10.1016/j.jnoncrysol.2022.121994]
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