The potential of sebacic acid as a corrosion inhibitor for hot‐dip galvanized steel in 0.1 M NaCl solution has been investigated. Different concentrations of the organic acid have been tested in order to understand the inhibition mechanism of the compound. The electrochemical test revealed a competitive mechanism between the dissolution of the metal in the acidified solution and the inhibition provided by the dicarboxylic species. The formation of a whitish layer consisting of zinc carboxylates and corrosion products was proved by means of scanning electron microscopy (SEM) investigation combined with Fourier transform infrared (FT‐IR) analysis. A bidentate bridging coordination between the Zn(II) and the carboxylic species is suggested.
Sebacic acid as corrosion inhibitor for hot-dip galvanized (HDG) steel in 0.1 M NaCl / Fedel, Michele; Poelman, Mireille; Olivier, Marjorie; Deflorian, Flavio. - In: SURFACE AND INTERFACE ANALYSIS. - ISSN 0142-2421. - STAMPA. - 2019, 51:5(2019), pp. 541-551. [10.1002/sia.6617]
Sebacic acid as corrosion inhibitor for hot-dip galvanized (HDG) steel in 0.1 M NaCl
Fedel, Michele;Deflorian, Flavio
2019-01-01
Abstract
The potential of sebacic acid as a corrosion inhibitor for hot‐dip galvanized steel in 0.1 M NaCl solution has been investigated. Different concentrations of the organic acid have been tested in order to understand the inhibition mechanism of the compound. The electrochemical test revealed a competitive mechanism between the dissolution of the metal in the acidified solution and the inhibition provided by the dicarboxylic species. The formation of a whitish layer consisting of zinc carboxylates and corrosion products was proved by means of scanning electron microscopy (SEM) investigation combined with Fourier transform infrared (FT‐IR) analysis. A bidentate bridging coordination between the Zn(II) and the carboxylic species is suggested.File | Dimensione | Formato | |
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Surf Interface Anal. 2019;1–11..pdf
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