tNovel UV-light curable methacrylic-siloxane-cellulose composite coatings for wood protection were pre-pared, fully characterized and, then, applied on walnut wood samples in order to assess the potentialprotective performances of the wooden treated substrates, such as hydrophobicity and surface prop-erties. A comparison between nanocellulose and microcellulose filled coatings (5 and 10 wt%) was alsoperformed. Thermal-mechanical analysis highlighted the higher effectiveness of nanocellulose in increas-ing the glass transition temperature, improving thermal and dimensional stability and stiffness of theneat photoresin with respect to microcellulose. A more pronounced increase of hydrophobicity (contactangle and water capillarity), surface hardness (Shore D and pencil scratch tests) of the neat UV-lightcured matrix filled with nanocellulose and applied on wood was, finally, observed in comparison tomicrocellulose composites. © 2017 Elsevier B.V. All rights reserved.
Novel UV-light curable methacrylic-siloxane-cellulose composite coatings for wood protection were prepared, fully characterized and, then, applied on walnut wood samples in order to assess the potential protective performances of the wooden treated substrates, such as hydrophobicity and surface properties. A comparison between nanocellulose and microcellulose filled coatings (5 and 10 wt%) was also performed. Thermal-mechanical analysis highlighted the higher effectiveness of nanocellulose in increasing the glass transition temperature, improving thermal and dimensional stability and stiffness of the neat photoresin with respect to microcellulose. A more pronounced increase of hydrophobicity (contact angle and water capillarity), surface hardness (Shore D and pencil scratch tests) of the neat UV-light cured matrix filled with nanocellulose and applied on wood was, finally, observed in comparison to microcellulose composites.
Photocurable resin/nanocellulose composite coatings for wood protection / Cataldi, A., Esposito Corcione, C., Frigione, M., Pegoretti, A.. - In: PROGRESS IN ORGANIC COATINGS. - ISSN 0300-9440. - STAMPA. - 106:(2017), pp. 128-136. [10.1016/j.porgcoat.2017.01.019]
Photocurable resin/nanocellulose composite coatings for wood protection
Cataldi, Annalisa;Pegoretti, Alessandro
2017-01-01
Abstract
Novel UV-light curable methacrylic-siloxane-cellulose composite coatings for wood protection were prepared, fully characterized and, then, applied on walnut wood samples in order to assess the potential protective performances of the wooden treated substrates, such as hydrophobicity and surface properties. A comparison between nanocellulose and microcellulose filled coatings (5 and 10 wt%) was also performed. Thermal-mechanical analysis highlighted the higher effectiveness of nanocellulose in increasing the glass transition temperature, improving thermal and dimensional stability and stiffness of the neat photoresin with respect to microcellulose. A more pronounced increase of hydrophobicity (contact angle and water capillarity), surface hardness (Shore D and pencil scratch tests) of the neat UV-light cured matrix filled with nanocellulose and applied on wood was, finally, observed in comparison to microcellulose composites.| File | Dimensione | Formato | |
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4-Photocurable resin:nanocellulose .pdf
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