Three new secondary metabolites (named erythrolactones A2, B2 and C2), that are characterized by a central 4-hydroxy-unsaturated δ lactone ring bearing an alkyl saturated chain at C(2) and a butyl-benzenoid group at C(5), together with their respective sulfate esters (erythrolactones A1, B1 and C1), have been isolated from cell cultures of Pseudokeronopsis erythrina, clone TL-1. The structures are assigned on the basis of extensive spectroscopic measurements (1D and 2D NMR, UV,IR and HR-MALDI-TOF). A plausible biogenetic route for their formation is also suggested. Cold-shock treatment was performed in order to induce the discharge of the metabolites contained in pigment granules lying on the ciliary organelles of this microorganism. HPLC-ESI-MS analysis of this granule discharge reveals that erythrolactones A2–C2 are actually therein contained, strongly suggesting a possible role for these metabolites in the chemical defence strategy of P. erythrina.
Metabolites from the Euryhaline CiliatePseudokeronopsis erythrina / Anesi, A.; Buonanno, F.; di Giuseppe, G.; Ortenzi, C.; Guella, G.. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - 2016:7(2016), pp. 1330-1336.
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Titolo: | Metabolites from the Euryhaline CiliatePseudokeronopsis erythrina |
Autori: | Anesi, A.; Buonanno, F.; di Giuseppe, G.; Ortenzi, C.; Guella, G. |
Autori Unitn: | |
Titolo del periodico: | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY |
Anno di pubblicazione: | 2016 |
Numero e parte del fascicolo: | 7 |
Codice identificativo Scopus: | 2-s2.0-84959917042 |
Codice identificativo ISI: | WOS:000372848000016 |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/ejoc.201501424 |
Handle: | http://hdl.handle.net/11572/135569 |
Citazione: | Metabolites from the Euryhaline CiliatePseudokeronopsis erythrina / Anesi, A.; Buonanno, F.; di Giuseppe, G.; Ortenzi, C.; Guella, G.. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - STAMPA. - 2016:7(2016), pp. 1330-1336. |
Appare nelle tipologie: | 03.1 Articolo su rivista (Journal article) |
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