Green Monopropellants

Green propellants are usually defined as low-hazard, low-toxicity, environmentally friendly propellants that are considered safe during various phases of spacecraft development, launch, and operations. Such propellants provide safe handling and storability when compared to conventional toxic propellants such as hydrazine and its derivatives that require special handling protocols and adhering to strict safety measurements that, in addition to others, include using Self-Contained Atmospheric Protective Ensemble (SCAPE) suits. Due to their favorable characteristics, green propellants demonstrate higher commercial value by being able to cut costs related to transportation, storage, handling, and further reduces ground operations time. Recently, a more specified definition has been noted by Mayer et al. (2018) [3], based on the Acute Toxicity Classification (ATC) by the Global Harmonized System of classification and labeling of chemicals (GHS) [6], which denotes that propellants possessing ATC levels of three and safer are considered as green propellants. ATC levels are typically categorized on a 1:5 scale where level one denotes the most toxic class and level five is considered the least toxic class. Moreover, a controversial topic arises when referring to some modern green propellants, whether to address them by the term “monopropellants” or by more specific terms including (premixed propellants, fuel blends, or mixtures). Monopropellants are fundamentally defined as propellants consisting of chemical compounds (for example N2H4), which release energy through exothermic chemical decomposition. Since the evolution of liquid gun propellants based on HAN compound and other nitrate salts aqueous solutions, the term “monopropellants” was used to describe such premixed formulations. As widely used in literature and industry, some modern green propellants, for instance the Energetic Ionic Liquids (EILs), are undoubtedly classified and described as “monopropellants.” Basically, it can be interpreted from the previous that a "green monopropellant" may be defined as: "A low-hazard, low-toxicity, and safe-to handle propellant that is stored in a single tank and is able to decompose from its storage state by the help of a catalyst or other ignition method, such as thermal or electric ignition, can be considered a “green monopropellant” as long as it does not require another separately stored propellant for decomposition."