ABSTRACT The here proposed halo-catenated electrolytes consist of a complex network formed by different molecular units bridged together by halogen atoms. The components constituting the electrolytes are generally three: 1) a molten salt (MS); 2) a Lewis acid multivalent metal halide salt (AXw); and 3) a Lewis acid alkaline earth metal halide salt (BY2). The resulting formula of the here proposed electrolytes is MS-(AXw)n-(BY2)m, where MS is a molten salt composed by a halogen anion (e.g. F-, Cl-, Br-, or I-) and an organic cation (e.g. belonging to the family of pyridinium, imidazolium, or pyrrolidinium); A is Ti, B, Ti, Mn, Fe, Ni, Co, Ag, Au, or Al; X and Y are halogen anions (F-, Cl-, Br-, or I-); and B is an alkaline earth metal (Mg2+). The proposed materials are included as electrolytes in cells consisting of at least one anode, at least one cathode, a separator, and current collectors. The anode consists of at least one of A or B, or an alloy of the two, in the metal state (A0, B0). The so obtained devices are charged and discharged under galvanostatic conditions for several cycles.

Halo-Catenated Electrolytes for Hybrid Lewis Acid Divalent and Multivalent Metal-Based Primary and Secondary Batteries / Di Noto, V.; Fauri, M.; Pagot, G.; Bertasi., F.. - (2019).

Halo-Catenated Electrolytes for Hybrid Lewis Acid Divalent and Multivalent Metal-Based Primary and Secondary Batteries

M. Fauri;
2019

Abstract

ABSTRACT The here proposed halo-catenated electrolytes consist of a complex network formed by different molecular units bridged together by halogen atoms. The components constituting the electrolytes are generally three: 1) a molten salt (MS); 2) a Lewis acid multivalent metal halide salt (AXw); and 3) a Lewis acid alkaline earth metal halide salt (BY2). The resulting formula of the here proposed electrolytes is MS-(AXw)n-(BY2)m, where MS is a molten salt composed by a halogen anion (e.g. F-, Cl-, Br-, or I-) and an organic cation (e.g. belonging to the family of pyridinium, imidazolium, or pyrrolidinium); A is Ti, B, Ti, Mn, Fe, Ni, Co, Ag, Au, or Al; X and Y are halogen anions (F-, Cl-, Br-, or I-); and B is an alkaline earth metal (Mg2+). The proposed materials are included as electrolytes in cells consisting of at least one anode, at least one cathode, a separator, and current collectors. The anode consists of at least one of A or B, or an alloy of the two, in the metal state (A0, B0). The so obtained devices are charged and discharged under galvanostatic conditions for several cycles.
Halo-Catenated Electrolytes for Hybrid Lewis Acid Divalent and Multivalent Metal-Based Primary and Secondary Batteries / Di Noto, V.; Fauri, M.; Pagot, G.; Bertasi., F.. - (2019).
Di Noto, V.; Fauri, M.; Pagot, G.; Bertasi., F.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11572/262590
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact