For the first time, multifunctional fully biodegradable composites combining structural and thermal energy storage/release capabilities were prepared and thermo-mechanically characterized. Within this scope, thin beech laminae impregnated with a phase change material (PCM) represented by poly(ethylene glycol) (PEG) were interleaved with thin foils of thermoplastic starch (TPS) and consolidated by hot pressing. From scanning electron microscopy, it was observed that a certain amount of PEG (about 11 wt% of the total laminate) remained entrapped within the wood pores, negatively affecting the interfacial adhesion between wood laminae and TPS foils. The presence of PEG stabilized in the wood laminae was confirmed by differential scanning calorimetry tests, in which a specific melting enthalpy of 27.4 J/g was detected with amelting peak at 55 degrees C. Wood permeation with PEG was responsible for an increase of the dynamic moduli E' and E '', as well as of the tensile and Charpy impact strength of the laminates. Therefore, this paper highlighted the possibility of developing multifunctional fully biodegradable composites capable of combining structural and thermal energy storage properties, in which the selected PCM positively contributed to the mechanical behavior of the laminates.

Thermo-mechanical behavior of novel wood laminae-thermoplastic starch biodegradable composites with thermal energy storage/release capability / Dorigato, A.; Fredi, G.; Pegoretti, A.. - In: FRONTIERS IN MATERIALS. - ISSN 2296-8016. - 6:(2019). [10.3389/fmats.2019.00076]

Thermo-mechanical behavior of novel wood laminae-thermoplastic starch biodegradable composites with thermal energy storage/release capability

Dorigato A.;Fredi G.;Pegoretti A.
2019-01-01

Abstract

For the first time, multifunctional fully biodegradable composites combining structural and thermal energy storage/release capabilities were prepared and thermo-mechanically characterized. Within this scope, thin beech laminae impregnated with a phase change material (PCM) represented by poly(ethylene glycol) (PEG) were interleaved with thin foils of thermoplastic starch (TPS) and consolidated by hot pressing. From scanning electron microscopy, it was observed that a certain amount of PEG (about 11 wt% of the total laminate) remained entrapped within the wood pores, negatively affecting the interfacial adhesion between wood laminae and TPS foils. The presence of PEG stabilized in the wood laminae was confirmed by differential scanning calorimetry tests, in which a specific melting enthalpy of 27.4 J/g was detected with amelting peak at 55 degrees C. Wood permeation with PEG was responsible for an increase of the dynamic moduli E' and E '', as well as of the tensile and Charpy impact strength of the laminates. Therefore, this paper highlighted the possibility of developing multifunctional fully biodegradable composites capable of combining structural and thermal energy storage properties, in which the selected PCM positively contributed to the mechanical behavior of the laminates.
2019
Dorigato, A.; Fredi, G.; Pegoretti, A.
Thermo-mechanical behavior of novel wood laminae-thermoplastic starch biodegradable composites with thermal energy storage/release capability / Dorigato, A.; Fredi, G.; Pegoretti, A.. - In: FRONTIERS IN MATERIALS. - ISSN 2296-8016. - 6:(2019). [10.3389/fmats.2019.00076]
File in questo prodotto:
File Dimensione Formato  
220-Dorigato_FMats-2019.pdf

accesso aperto

Tipologia: Versione editoriale (Publisher’s layout)
Licenza: Creative commons
Dimensione 2.49 MB
Formato Adobe PDF
2.49 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11572/244785
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 33
  • ???jsp.display-item.citation.isi??? 27
social impact