The aim of this work is to apply Hydrothermal Carbonisation (HTC) to different kinds of sludge such as thickened sludge, digested sludge and dewatered sludge, and compare the composition of the solid produced by the process, i.e. hydrochar, with soil and biosolid legislations: Table 1. For the purpose, experimental tests were performed at different operating conditions, namely three temperatures (190, 220 and 250 °C) and two reaction times (30 and 60 minutes). The different kinds of sludge were fed to a 50 mL s.s. batch reactor capable to withstand high pressure (140 bar) and temperature (300 °C) and, after the process, hydrochar was separated from the HTC process liquid through paper filtration and subsequently dried. Apparatus and procedures were previously fully described [1]. The hydrochars from HTC at different operative conditions were characterized in terms of ultimate, proximate and ICP-OES analyses. The resulting chars have an ash content between 18 and 79 wt%, a C content between 10 and 46 wt%, a N content between 2 and 7wt% (all values on a dry basis, d.b.), a P, Mg, Na, K and Ca content of several g/kg, a Pb, Cd, Ni, Zn, Cu, Hg, Cr, As and Co content of the order of mg/kg (Table 1). The HTC process tends to concentrate P, Mg and Ca and reduce K and Na content in the hydrochar in respect to the initial dry sludge, due to the high solubility of K and Na in the water phase. Hydrochars have a higher content in heavy metals than the initial sludge due to their extremely low solubility in the water phase and substantial overall solid mass reduction. Such mass reduction is due to the degradation of the organic fraction during the HTC process.

Hydrothermal carbonisation of sewage sludge: char characterisation and reference to international legislations / Merzari, F.; Andreottola, G.; Volpe, M.; Valentinuzzi, F.; Mimmo, T.; Cesco, S.; Fiori, L.. - ELETTRONICO. - (2017), pp. 27-27. (Intervento presentato al convegno Biochar: Production, Characterization and Applications tenutosi a Alba, Cuneo, Italia nel 20-25 August 2017).

Hydrothermal carbonisation of sewage sludge: char characterisation and reference to international legislations

F. Merzari;G. Andreottola;M. Volpe;L. Fiori
2017-01-01

Abstract

The aim of this work is to apply Hydrothermal Carbonisation (HTC) to different kinds of sludge such as thickened sludge, digested sludge and dewatered sludge, and compare the composition of the solid produced by the process, i.e. hydrochar, with soil and biosolid legislations: Table 1. For the purpose, experimental tests were performed at different operating conditions, namely three temperatures (190, 220 and 250 °C) and two reaction times (30 and 60 minutes). The different kinds of sludge were fed to a 50 mL s.s. batch reactor capable to withstand high pressure (140 bar) and temperature (300 °C) and, after the process, hydrochar was separated from the HTC process liquid through paper filtration and subsequently dried. Apparatus and procedures were previously fully described [1]. The hydrochars from HTC at different operative conditions were characterized in terms of ultimate, proximate and ICP-OES analyses. The resulting chars have an ash content between 18 and 79 wt%, a C content between 10 and 46 wt%, a N content between 2 and 7wt% (all values on a dry basis, d.b.), a P, Mg, Na, K and Ca content of several g/kg, a Pb, Cd, Ni, Zn, Cu, Hg, Cr, As and Co content of the order of mg/kg (Table 1). The HTC process tends to concentrate P, Mg and Ca and reduce K and Na content in the hydrochar in respect to the initial dry sludge, due to the high solubility of K and Na in the water phase. Hydrochars have a higher content in heavy metals than the initial sludge due to their extremely low solubility in the water phase and substantial overall solid mass reduction. Such mass reduction is due to the degradation of the organic fraction during the HTC process.
2017
Biochar: Production, Characterization and Applications - Abstracts Booklet
Alba, Cuneo, Italia
ECI
Hydrothermal carbonisation of sewage sludge: char characterisation and reference to international legislations / Merzari, F.; Andreottola, G.; Volpe, M.; Valentinuzzi, F.; Mimmo, T.; Cesco, S.; Fiori, L.. - ELETTRONICO. - (2017), pp. 27-27. (Intervento presentato al convegno Biochar: Production, Characterization and Applications tenutosi a Alba, Cuneo, Italia nel 20-25 August 2017).
Merzari, F.; Andreottola, G.; Volpe, M.; Valentinuzzi, F.; Mimmo, T.; Cesco, S.; Fiori, L.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11572/195128
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